40ar 39ar dating method

Radiometric Dating Does Work! Radiometric dating of rocks and minerals using naturally occurring, long-lived radioactive isotopes is troublesome for young-earth creationists because the techniques have provided overwhelming evidence of the antiquity of the earth and life.

Some so-called creation scientists have attempted to show that radiometric dating does not work on theoretical grounds for example, Arndts and Overn ; Gill but such attempts invariably have fatal flaws see Dalrymple ; York and Dalrymple Other creationists have focused on instances in which radiometric dating seems to yield incorrect results.

In most instances, these efforts are flawed because the authors have misunderstood or misrepresented the data they attempt to analyze for example, Woodmorappe ; Morris HM ; Morris JD Only rarely does a creationist actually find an incorrect radiometric result Austin ; Rugg and Austin that has not already been revealed and discussed in the scientific literature.

The creationist approach of focusing on examples where radiometric dating yields incorrect results is a curious one for two reasons. First, it provides no evidence whatsoever to support their claim that the earth is very young. If the earth were only 10 years old, then surely there should be some scientific evidence to confirm that hypothesis; yet the creationists have produced not a shred of it so far.

Where are the data and age calculations that result in a consistent set of ages for all rocks on earth, as well as those from the moon and the meteorites, no greater than 10 years?

Glaringly absent, it seems. Second, it is an approach doomed to failure at the outset. Creationists seem to think that a few examples of incorrect radiometric ages invalidate all of the results of radiometric dating, but such a conclusion is illogical. Even things that work well do not work well all of the time and under all circumstances.

Try, for example, wearing a watch that is not waterproof while swimming. It will probably fail, but what would a reasonable person conclude from that? That watches do not work? A few verified examples of incorrect radiometric ages are simply insufficient to prove that radiometric dating is invalid.

All they indicate is that the methods are not infallible. Those of us who have developed and used dating techniques to solve scientific problems are well aware that the systems are not perfect; we ourselves have provided numerous examples of instances in which the techniques fail.

We often test them under controlled conditions to learn when and why they fail so we will not use them incorrectly. We have even discredited entire techniques. For example, after extensive testing over many years, it was concluded that uranium-helium dating is highly unreliable because the small helium atom diffuses easily out of minerals over geologic time.

As a result, this method is not used except in rare and highly specialized applications. These methods provide valuable and valid age data in most instances, although there is a small percentage of cases in which even these generally reliable methods yield incorrect results. Such failures may be due to laboratory errors mistakes happen , unrecognized geologic factors nature sometimes fools us , or misapplication of the techniques no one is perfect.

Not only that, they have to show the flaws in those dating studies that provide independent corroborative evidence that radiometric methods work. This is a tall order and the creationists have made no progress so far. It is rare for a study involving radiometric dating to contain a single determination of age. Usually determinations of age are repeated to avoid laboratory errors, are obtained on more than one rock unit or more than one mineral from a rock unit in order to provide a cross-check, or are evaluated using other geologic information that can be used to test and corroborate the radiometric ages.

Scientists who use radiometric dating typically use every means at their disposal to check, recheck, and verify their results, and the more important the results the more they are apt to be checked and rechecked by others. As a result, it is nearly impossible to be completely fooled by a good set of radiometric age data collected as part of a well-designed experiment.

The purpose of this paper is to describe briefly a few typical radiometric dating studies, out of hundreds of possible examples documented in the scientific literature, in which the ages are validated by other available information. I have selected four examples from recent literature, mostly studies involving my work and that of a few close colleagues because it was easy to do so.

I could have selected many more examples but then this would have turned into a book rather than the intended short paper. The heat of the impact melted some of the feldspar crystals in the granitic rocks of the impact zone, thereby resetting their internal radiometric clocks.

The impact also created shocked quartz crystals that were blasted into the air and subsequently fell to the west into the inland sea that occupied much of central North America at that time.

Today this shocked quartz is found in South Dakota, Colorado, and Nebraska in a thin layer the Crow Creek Member within a thick rock formation known as the Pierre Shale. The Pierre Shale, which is divided into identifiable sedimentary beds called members, also contains abundant fossils of numerous species of ammonites, ancestors of the chambered nautilus.

The fossils, when combined with geologic mapping, allow the various exposed sections of the Pierre Shale to be pieced together in their proper relative positions to form a complete composite section Figure 1. The Pierre Shale also contains volcanic ash that was erupted from volcanoes and then fell into the sea, where it was preserved as thin beds.

There are three important things to note about these results. First, each age is based on numerous measurements; laboratory errors, had there been any, would be readily apparent. Second, ages were measured on two very different minerals, sanidine and biotite, from several of the ash beds.

Third, the radiometric ages agree, within analytical error, with the relative positions of the dated ash beds as determined by the geologic mapping and the fossil assemblages; that is, the ages get older from top to bottom as they should.

Finally, the inferred age of the shocked quartz, as determined from the age of the melted feldspar in the Manson impact structure The Ages of Meteorites Meteorites, most of which are fragments of asteroids, are very interesting objects to study because they provide important evidence about the age, composition, and history of the early solar system.

There are many types of meteorites. Some are from primitive asteroids whose material is little modified since they formed from the early solar nebula. Others are from larger asteroids that got hot enough to melt and send lava flows to the surface.

A few are even from the Moon and Mars. The most primitive type of meteorites are called chondrites, because they contain little spheres of olivine crystals known as chondrules. Because of their importance, meteorites have been extensively dated radiometrically; the vast majority appear to be 4. Some meteorites, because of their mineralogy, can be dated by more than one radiometric dating technique, which provides scientists with a powerful check of the validity of the results.

The results from three meteorites are shown in Table 1. Many more, plus a discussion of the different types of meteorites and their origins, can be found in Dalrymple There are 3 important things to know about the ages in Table 1. The first is that each meteorite was dated by more than one laboratory Allende by 2 laboratories, Guarena by 2 laboratories, and St Severin by four laboratories.

This pretty much eliminates any significant laboratory biases or any major analytical mistakes. The second thing is that some of the results have been repeated using the same technique, which is another check against analytical errors.

The third is that all three meteorites were dated by more than one method two methods each for Allende and Guarena, and four methods for St Severin. This is extremely powerful verification of the validity of both the theory and practice of radiometric dating. In the case of St Severin, for example, we have 4 different natural clocks actually 5, for the Pb-Pb method involves 2 different radioactive uranium isotopes , each running at a different rate and each using elements that respond to chemical and physical conditions in much different ways.

And yet, they all give the same result to within a few percent. Is this a remarkable coincidence? Scientists have concluded that it is not; it is instead a consequence of the fact that radiometric dating actually works and works quite well.

Creationists who wants to dispute the conclusion that primitive meteorites, and therefore the solar system, are about 4. The K-T Tektites One of the most exciting and important scientific findings in decades was the discovery that a large asteroid, about 10 kilometers diameter, struck the earth at the end of the Cretaceous Period. The collision threw many tons of debris into the atmosphere and possibly led to the extinction of the dinosaurs and many other life forms.

The fallout from this enormous impact, including shocked quartz and high concentrations of the element iridium, has been found in sedimentary rocks at more than locations worldwide at the precise stratigraphic location of the Cretaceous-Tertiary K-T boundary Alvarez and Asaro ; Alvarez We now know that the impact site is located on the Yucatan Peninsula.

Measuring the age of this impact event independently of the stratigraphic evidence is an obvious test for radiometric methods, and a number of scientists in laboratories around the world set to work. In addition to shocked quartz grains and high concentrations of iridium, the K-T impact produced tektites, which are small glass spherules that form from rock that is instantaneously melted by a large impact.

The K-T tektites were ejected into the atmosphere and deposited some distance away. Tektites are easily recognizable and form in no other way, so the discovery of a sedimentary bed the Beloc Formation in Haiti that contained tektites and that, from fossil evidence, coincided with the K-T boundary provided an obvious candidate for dating. Scientists from the US Geological Survey were the first to obtain radiometric ages for the tektites and laboratories in Berkeley, Stanford, Canada, and France soon followed suit.

The results from all of the laboratories were remarkably consistent with the measured ages ranging only from Similar tektites were also found in Mexico, and the Berkeley lab found that they were the same age as the Haiti tektites. The K-T boundary is recorded in numerous sedimentary beds around the world.

Numerous thin beds of volcanic ash occur within these coals just centimeters above the K-T boundary, and some of these ash beds contain minerals that can be dated radiometrically. Since both the ash beds and the tektites occur either at or very near the K-T boundary, as determined by diagnostic fossils, the tektites and the ash beds should be very nearly the same age, and they are Table 2.

There are several important things to note about these results. First, the Cretaceous and Tertiary periods were defined by geologists in the early s. The boundary between these periods the K-T boundary is marked by an abrupt change in fossils found in sedimentary rocks worldwide. Its exact location in the stratigraphic column at any locality has nothing to do with radiometric dating it is located by careful study of the fossils and the rocks that contain them, and nothing more.

Furthermore, the dating was done in 6 different laboratories and the materials were collected from 5 different locations in the Western Hemisphere. And yet the results are the same within analytical error. These flows buried and destroyed Pompeii and other nearby Roman cities. We know the exact day of this eruption because Pliny the Younger carefully recorded the event. They separated sanidine crystals from a sample of one of the ash flows. Incremental heating experiments on 12 samples of sanidine yielded 46 data points that resulted in an isochron age of 94 years.

The actual age of the flow in was years. Is this just a coincidence? No it is the result of extremely careful analyses using a technique that works. This is not the only dating study to be done on an historic lava flow. Two extensive studies done more than 25 years ago involved analyzing the isotopic composition of argon in such flows to determine if the source of the argon was atmospheric, as must be assumed in K-Ar dating Dalrymple , 26 flows; Krummenacher , 19 flows.

Note, however, that even an error of 0. Summary In this short paper I have briefly described 4 examples of radiometric dating studies where there is both internal and independent evidence that the results have yielded valid ages for significant geologic events. It is these studies, and the many more like them documented in the scientific literature, that the creationists need to address before they can discredit radiometric dating.


As for any isotopic dating method, closed-system behavior of the selected minerals is required for the two KAr and 40 Ar/ 39 Ar dating methods. This requirement is, of course, especially crucial for Ar, which is not bonded to other atoms or ions in a mineral structure like most of the classical cations of the basic isotopic dating methods, such as Sr, Nd, or Pb. The 40Ar/39Ar dating technique is a variation on this method and involves the irradiation of a sample resulting in the conversion of 39K to 39Ar (Mitchell, ). Since the ratio of 39K/40K is constant, the pre-irradiation concentration of 40K in a sample can be determined by measuring the 39Ar which is produced during irradiation.

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